User:Herravondure/sandbox

[[File:UiO-66 framework structure.png|thumb|Crystal structure of UiO-66 (top), the structure rotated by 45° (middle), and the zirconium oxo cluster with twelve attached terepthalic acid ligands (bottom) with hydrogens omitted. Turquoise: zirconium, red: oxygen, grey: carbon.]]

[[File:UiO-66 framework structure.png|thumb|Crystal structure of UiO-66 (top), the structure rotated by 45° (middle), and the zirconium oxo cluster with twelve attached terepthalic acid ligands (bottom) with hydrogens omitted. Turquoise: zirconium, red: oxygen, grey: carbon.]]

UiO ([[University of Oslo]]) series frameworks are a group of [[Metal–organic framework|metal-organic frameworks]] (MOFs) that were first discovered in 2008{{Cite journal |last=Cavka|first=Jasmina Hafizovic|last2=Jakobsen|first2=Søren|last3=Olsbye|first3=Unni|last4=Guillou|first4=Nathalie|last5=Lamberti|first5=Carlo|last6=Bordiga|first6=Silvia|last7=Lillerud|first7=Karl Petter|date=2008-10-22|title=A New Zirconium Inorganic Building Brick Forming Metal Organic Frameworks with Exceptional Stability|url=https://pubs.acs.org/doi/10.1021/ja8057953|journal=Journal of the American Chemical Society|language=en|volume=130|issue=42|pages=13850–13851|doi=10.1021/ja8057953|issn=0002-7863}} with the general formula Zr₆O₄(OH)₄(L)₆, where L is an organic [[ligand]]. UiO series MOFs contain zirconium oxo clusters that adopt a octrahedral geometry with zirconium present in each of its vertices. In pristine UiO MOFs, each cluster binds to twelve organic ligands, but these MOFs are also stable with missing organic linkers, or defect sites.{{Cite journal |last=Kaur|first=Gurpreet|last2=Øien-Ødegaard|first2=Sigurd|last3=Lazzarini|first3=Andrea|last4=Chavan|first4=Sachin Maruti|last5=Bordiga|first5=Silvia|last6=Lillerud|first6=Karl Petter|last7=Olsbye|first7=Unni|date=2019-08-07|title=Controlling the Synthesis of Metal–Organic Framework UiO-67 by Tuning Its Kinetic Driving Force|url=https://pubs.acs.org/doi/10.1021/acs.cgd.9b00916|journal=Crystal Growth & Design|language=en|volume=19|issue=8|pages=4246–4251|doi=10.1021/acs.cgd.9b00916|issn=1528-7483}} Non-modified UiO series MOFs have Fm3m symmetry. The zirconium oxo clusters with the bridging μ₃-OH, has D_3d symmetry.

UiO ([[University of Oslo]]) series frameworks are a group of [[Metal–organic framework|metal-organic frameworks]] (MOFs) that were first discovered in 2008{{Cite journal |last=Cavka|first=Jasmina Hafizovic|last2=Jakobsen|first2=Søren|last3=Olsbye|first3=Unni|last4=Guillou|first4=Nathalie|last5=Lamberti|first5=Carlo|last6=Bordiga|first6=Silvia|last7=Lillerud|first7=Karl Petter|date=2008-10-22|title=A New Zirconium Inorganic Building Brick Forming Metal Organic Frameworks with Exceptional Stability|url=https://pubs.acs.org/doi/10.1021/ja8057953|journal=Journal of the American Chemical Society|language=en|volume=130|issue=42|pages=13850–13851|doi=10.1021/ja8057953|issn=0002-7863}} with the general formula Zr₆O₄(OH)₄(L)₆, where L is an organic [[ligand]]. UiO series MOFs contain zirconium oxo clusters that adopt a octrahedral geometry with zirconium present in each of its vertices. In pristine UiO MOFs, each cluster binds to twelve organic ligands, but these MOFs are also stable with missing organic linkers, or defect sites.{{Cite journal |last=Kaur|first=Gurpreet|last2=Øien-Ødegaard|first2=Sigurd|last3=Lazzarini|first3=Andrea|last4=Chavan|first4=Sachin Maruti|last5=Bordiga|first5=Silvia|last6=Lillerud|first6=Karl Petter|last7=Olsbye|first7=Unni|date=2019-08-07|title=Controlling the Synthesis of Metal–Organic Framework UiO-67 by Tuning Its Kinetic Driving Force|url=https://pubs.acs.org/doi/10.1021/acs.cgd.9b00916|journal=Crystal Growth & Design|language=en|volume=19|issue=8|pages=4246–4251|doi=10.1021/acs.cgd.9b00916|issn=1528-7483}} Non-modified UiO series MOFs have a Fm3m space group. The zirconium oxo clusters with the bridging μ₃-OH, has D_3d symmetry.

The series is made up of 4 members that differ in the number of [[Phenyl group|phenyl]] rings in their organic linkers. The organic linkers are [[Terephthalic acid|terepthalic acid]], biphenyl-4,4′-dicarboxylic acid, ''p''-Terphenyl-4,4''-dicarboxylic acid, and quaterphenyl dicarboxylic acid for UiO-66, UiO-67, Ui-68, and UiO-69, respectively. The UiO series of MOFs have seen significant research interest because of their high thermal (450-500 °C), chemical stability, tunable pore size, and high accessible surface area.{{Cite journal |last=Zhou|first=Ji|last2=Gu|first2=Shuangxi|last3=Xiang|first3=Yuqin|last4=Xiong|first4=Yun|last5=Liu|first5=Genyan|date=2025|title=UiO-67: A versatile metal-organic framework for diverse applications|url=https://linkinghub.elsevier.com/retrieve/pii/S0010854524007008|journal=Coordination Chemistry Reviews|language=en|volume=526|pages=216354|doi=10.1016/j.ccr.2024.216354}} UiO series MOFs with modified organic linkers or new ligands added into defect sites have seen great interest in material science for applications including radionuclide remediation,{{Cite journal |last=Park |first=Kyoung Chul |last2=Lim |first2=Jaewoong |last3=Thaggard |first3=Grace C. |last4=Maldeni Kankanamalage |first4=Buddhima K. P. |last5=Lehman-Andino |first5=Ingrid |last6=Liu |first6=Yuan |last7=Burrell |first7=Jennii M. |last8=Martin |first8=Corey R. |last9=Ta |first9=An T. |last10=Greytak |first10=Andrew B. |last11=Amoroso |first11=Jake W. |last12=DiPrete |first12=David D. |last13=Smith |first13=Mark D. |last14=Phillpot |first14=Simon R. |last15=Shustova |first15=Natalia B. |date=2025 |title=Stimuli-responsive photoswitch–actinide binding: a match made in MOFs |url=https://xlink.rsc.org/?DOI=D5SC03171K |journal=Chemical Science |language=en |volume=16 |issue=31 |pages=14115–14126 |doi=10.1039/D5SC03171K |issn=2041-6520 |pmc=12242833 |pmid=40656527}} catalysis,{{Cite journal |last=Pulumati |first=Sri Harsha |last2=Sannes |first2=Dag Kristian |last3=Jabbour |first3=Christia R. |last4=Mandemaker |first4=Laurens D. B. |last5=Weckhuysen |first5=Bert M. |last6=Olsbye |first6=Unni |last7=Nova |first7=Ainara |last8=Skúlason |first8=Egill |date=2024-01-05 |title=Mechanistic Insights in the Catalytic Hydrogenation of CO 2 over Pt Nanoparticles in UiO-67 Metal–Organic Frameworks |url=https://pubs.acs.org/doi/10.1021/acscatal.3c03401 |journal=ACS Catalysis |language=en |volume=14 |issue=1 |pages=382–394 |doi=10.1021/acscatal.3c03401 |issn=2155-5435}} and sensing.{{Cite journal |last=He |first=Zhijian |last2=Hu |first2=Jieying |last3=Zhong |first3=Jing |last4=Long |first4=Yunchen |last5=Shen |first5=Junda |last6=Chen |first6=Song |last7=Ou |first7=Weihui |last8=Liu |first8=Qiyu |last9=Lu |first9=Jian |last10=Lou |first10=Zaizhu |last11=Li |first11=Yang Yang |last12=He |first12=Jun |date=2025 |title=Plasmonic MOF for Highly Selective SERS Sensing of Trace Mercury (II) in Complex Matrices |url=https://onlinelibrary.wiley.com/doi/10.1002/smll.202409988 |journal=Small |language=en |volume=21 |issue=10 |doi=10.1002/smll.202409988 |issn=1613-6810}}

The series is made up of 4 members that differ in the number of [[Phenyl group|phenyl]] rings in their organic linkers. The organic linkers are [[Terephthalic acid|terepthalic acid]], biphenyl-4,4′-dicarboxylic acid, ''p''-Terphenyl-4,4''-dicarboxylic acid, and quaterphenyl dicarboxylic acid for UiO-66, UiO-67, Ui-68, and UiO-69, respectively. The UiO series of MOFs have seen significant research interest because of their high thermal (450-500 °C), chemical stability, tunable pore size, and high accessible surface area.{{Cite journal |last=Zhou|first=Ji|last2=Gu|first2=Shuangxi|last3=Xiang|first3=Yuqin|last4=Xiong|first4=Yun|last5=Liu|first5=Genyan|date=2025|title=UiO-67: A versatile metal-organic framework for diverse applications|url=https://linkinghub.elsevier.com/retrieve/pii/S0010854524007008|journal=Coordination Chemistry Reviews|language=en|volume=526|pages=216354|doi=10.1016/j.ccr.2024.216354}} UiO series MOFs with modified organic linkers or new ligands added into defect sites have seen great interest in material science for applications including radionuclide remediation,{{Cite journal |last=Park |first=Kyoung Chul |last2=Lim |first2=Jaewoong |last3=Thaggard |first3=Grace C. |last4=Maldeni Kankanamalage |first4=Buddhima K. P. |last5=Lehman-Andino |first5=Ingrid |last6=Liu |first6=Yuan |last7=Burrell |first7=Jennii M. |last8=Martin |first8=Corey R. |last9=Ta |first9=An T. |last10=Greytak |first10=Andrew B. |last11=Amoroso |first11=Jake W. |last12=DiPrete |first12=David D. |last13=Smith |first13=Mark D. |last14=Phillpot |first14=Simon R. |last15=Shustova |first15=Natalia B. |date=2025 |title=Stimuli-responsive photoswitch–actinide binding: a match made in MOFs |url=https://xlink.rsc.org/?DOI=D5SC03171K |journal=Chemical Science |language=en |volume=16 |issue=31 |pages=14115–14126 |doi=10.1039/D5SC03171K |issn=2041-6520 |pmc=12242833 |pmid=40656527}} catalysis,{{Cite journal |last=Pulumati |first=Sri Harsha |last2=Sannes |first2=Dag Kristian |last3=Jabbour |first3=Christia R. |last4=Mandemaker |first4=Laurens D. B. |last5=Weckhuysen |first5=Bert M. |last6=Olsbye |first6=Unni |last7=Nova |first7=Ainara |last8=Skúlason |first8=Egill |date=2024-01-05 |title=Mechanistic Insights in the Catalytic Hydrogenation of CO 2 over Pt Nanoparticles in UiO-67 Metal–Organic Frameworks |url=https://pubs.acs.org/doi/10.1021/acscatal.3c03401 |journal=ACS Catalysis |language=en |volume=14 |issue=1 |pages=382–394 |doi=10.1021/acscatal.3c03401 |issn=2155-5435}} and sensing.{{Cite journal |last=He |first=Zhijian |last2=Hu |first2=Jieying |last3=Zhong |first3=Jing |last4=Long |first4=Yunchen |last5=Shen |first5=Junda |last6=Chen |first6=Song |last7=Ou |first7=Weihui |last8=Liu |first8=Qiyu |last9=Lu |first9=Jian |last10=Lou |first10=Zaizhu |last11=Li |first11=Yang Yang |last12=He |first12=Jun |date=2025 |title=Plasmonic MOF for Highly Selective SERS Sensing of Trace Mercury (II) in Complex Matrices |url=https://onlinelibrary.wiley.com/doi/10.1002/smll.202409988 |journal=Small |language=en |volume=21 |issue=10 |doi=10.1002/smll.202409988 |issn=1613-6810}} Defective sites in the MOFs tend to decrease the thermal and chemical stability of the structure.

== Synthesis ==

== Synthesis ==

== UiO analogs==

== UiO analogs==

Isoreticular structures of UiO MOFs have been made with other tetravalent metals including hafnium,{{Cite journal |last=Jakobsen |first=Søren |last2=Gianolio |first2=Diego |last3=Wragg |first3=David S. |last4=Nilsen |first4=Merete Hellner |last5=Emerich |first5=Hermann |last6=Bordiga |first6=Silvia |last7=Lamberti |first7=Carlo |last8=Olsbye |first8=Unni |last9=Tilset |first9=Mats |last10=Lillerud |first10=Karl Petter |date=2012-09-19 |title=Structural determination of a highly stable metal-organic framework with possible application to interim radioactive waste scavenging: Hf-UiO-66 |url=https://link.aps.org/doi/10.1103/PhysRevB.86.125429 |journal=Physical Review B |language=en |volume=86 |issue=12 |doi=10.1103/PhysRevB.86.125429 |issn=1098-0121}} cerium,{{Cite journal |last=Campanelli |first=Matteo |last2=Del Giacco |first2=Tiziana |last3=De Angelis |first3=Filippo |last4=Mosconi |first4=Edoardo |last5=Taddei |first5=Marco |last6=Marmottini |first6=Fabio |last7=D’Amato |first7=Roberto |last8=Costantino |first8=Ferdinando |date=2019-12-04 |title=Solvent-Free Synthetic Route for Cerium(IV) Metal–Organic Frameworks with UiO-66 Architecture and Their Photocatalytic Applications |url=https://pubs.acs.org/doi/10.1021/acsami.9b13730 |journal=ACS Applied Materials & Interfaces |language=en |volume=11 |issue=48 |pages=45031–45037 |doi=10.1021/acsami.9b13730 |issn=1944-8244}} and thorium.{{Cite journal |last=Li |first=Zi‐Jian |last2=Ju |first2=Yu |last3=Lu |first3=Huangjie |last4=Wu |first4=Xiaoling |last5=Yu |first5=Xinle |last6=Li |first6=Yongxin |last7=Wu |first7=Xiaowei |last8=Zhang |first8=Zhi‐Hui |last9=Lin |first9=Jian |last10=Qian |first10=Yuan |last11=He |first11=Ming‐Yang |last12=Wang |first12=Jian‐Qiang |date=2021-01-18 |title=Boosting the Iodine Adsorption and Radioresistance of Th‐UiO‐66 MOFs via Aromatic Substitution |url=https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/chem.202003621 |journal=Chemistry – A European Journal |language=en |volume=27 |issue=4 |pages=1286–1291 |doi=10.1002/chem.202003621 |issn=0947-6539}}

Isoreticular structures of UiO MOFs have been made with other [[Valence (chemistry)|tetravalent]] metals including [[hafnium]],{{Cite journal |last=Jakobsen |first=Søren |last2=Gianolio |first2=Diego |last3=Wragg |first3=David S. |last4=Nilsen |first4=Merete Hellner |last5=Emerich |first5=Hermann |last6=Bordiga |first6=Silvia |last7=Lamberti |first7=Carlo |last8=Olsbye |first8=Unni |last9=Tilset |first9=Mats |last10=Lillerud |first10=Karl Petter |date=2012-09-19 |title=Structural determination of a highly stable metal-organic framework with possible application to interim radioactive waste scavenging: Hf-UiO-66 |url=https://link.aps.org/doi/10.1103/PhysRevB.86.125429 |journal=Physical Review B |language=en |volume=86 |issue=12 |doi=10.1103/PhysRevB.86.125429 |issn=1098-0121}} [[cerium]],{{Cite journal |last=Campanelli |first=Matteo |last2=Del Giacco |first2=Tiziana |last3=De Angelis |first3=Filippo |last4=Mosconi |first4=Edoardo |last5=Taddei |first5=Marco |last6=Marmottini |first6=Fabio |last7=D’Amato |first7=Roberto |last8=Costantino |first8=Ferdinando |date=2019-12-04 |title=Solvent-Free Synthetic Route for Cerium(IV) Metal–Organic Frameworks with UiO-66 Architecture and Their Photocatalytic Applications |url=https://pubs.acs.org/doi/10.1021/acsami.9b13730 |journal=ACS Applied Materials & Interfaces |language=en |volume=11 |issue=48 |pages=45031–45037 |doi=10.1021/acsami.9b13730 |issn=1944-8244}} [[thorium]],{{Cite journal |last=Li |first=Zi‐Jian |last2=Ju |first2=Yu |last3=Lu |first3=Huangjie |last4=Wu |first4=Xiaoling |last5=Yu |first5=Xinle |last6=Li |first6=Yongxin |last7=Wu |first7=Xiaowei |last8=Zhang |first8=Zhi‐Hui |last9=Lin |first9=Jian |last10=Qian |first10=Yuan |last11=He |first11=Ming‐Yang |last12=Wang |first12=Jian‐Qiang |date=2021-01-18 |title=Boosting the Iodine Adsorption and Radioresistance of Th‐UiO‐66 MOFs via Aromatic Substitution |url=https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/chem.202003621 |journal=Chemistry – A European Journal |language=en |volume=27 |issue=4 |pages=1286–1291 |doi=10.1002/chem.202003621 |issn=0947-6539}} and [[plutonium]].{{Cite journal |last=Hastings |first=Ashley M. |last2=Ray |first2=Debmalya |last3=Jeong |first3=WooSeok |last4=Gagliardi |first4=Laura |last5=Farha |first5=Omar K. |last6=Hixon |first6=Amy E. |date=2020-05-20 |title=Advancement of Actinide Metal–Organic Framework Chemistry via Synthesis of Pu-UiO-66 |url=https://pubs.acs.org/doi/10.1021/jacs.0c01895 |journal=Journal of the American Chemical Society |language=en |volume=142 |issue=20 |pages=9363–9371 |doi=10.1021/jacs.0c01895 |issn=0002-7863}}

==References==

==References==